Los Angeles Dodgers (2000–2004)
With a lot of pressure riding on his now well-paid shoulders, Green struggled at times in 2000, his first season with Los Angeles. Still, he led the league in games played (with 162), and was fifth in the league in doubles with 44 (the second-highest total in Dodgers history), while driving in 99 runs. He also had one of the longest consecutive games on-base streaks in baseball history, at 53; five behind Duke Snider's modern day National League (NL) record. He hit home runs in five straight games; the only other Dodgers to achieve this feat are Roy Campanella (1950), Matt Kemp (2010), Adrián González (2014–15), Joc Pederson (2015) and Shohei Ohtani (2025). He hit .329 in late innings of close games.
Green had a career year in 2001, batting .297 (.331 with runners in scoring position) with a .598 slugging percentage (a career best), 49 home runs (a career best), 121 runs (7th in the league), 125 RBIs (a career best), 370 total bases (5th in the league), and 20 stolen bases. His 49 home runs set a Dodgers single-season record (a record which stood until Shohei Ohtani hit his 50th home run of the season on September 19, 2024), but only tied for fourth in the league, behind Barry Bonds, Sammy Sosa, and Luis González. For the fourth straight year he stole 20 or more bases, and batted .331 with runners in scoring position. Green came in sixth in voting for league MVP.
Green made headlines for two decisions that he made during the 2001 season. On September 26, he stood by his word and sat out a game for the first time in 415 games, to honor the most significant holiday on the Jewish calendar, Yom Kippur. He also made a second notable decision on September 26, donating his day's pay of $75,000 ($136,000 in 2025) to a charity for survivors of the New York 9/11 terrorist attacks.
Green started off slowly in 2002, but turned things around with a record-setting power display. On May 23, the turning point of his season, he had one of the best single game performances ever. He hit a Major League record-tying four home runs and a record-tying five extra-base hits (he hit a double in addition to the home runs) against the Milwaukee Brewers, and had 19 total bases, breaking Joe Adcock's 1954 Major League record by one, while matching the major league record of six runs scored in one game. This record has since been matched by Nick Kurtz in 2025. No other major league player had six hits, five runs, and as many as four extra-base hits in a game again until Ian Kinsler of the Texas Rangers in 2009. He hit a fifth home run during the following game to tie the Major League two-game home run record (five), and then hit two more the game after to break the Major League three-game record (seven). Green also broke the NL record with nine home runs in that calendar week. He was voted to the All-Star team, and finished the season with a .285 average, .385 On-base percentage (a career best), 42 home runs (third in the league), 114 RBIs (fourth in the league), 114 runs (fourth in the league), 93 walks (a career best), 22 intentional walks (fifth in the league), and 20 stolen bases. He hit .333 with runners in scoring position and two out. Green came in 5th in voting for league MVP.
In 2003, Green struggled with his power and RBI production. He had problems with tendinitis in his left shoulder, which limited him to a 19 home runs and 85 RBIs as he batted .280. Still, he was second in the league in doubles (with 49; a career best).
Green's power improved in 2004, as he hit 28 home runs and collected 86 RBIs, while batting .266, leading the Dodgers to the 2004 playoffs. Green moved to first base for much of the season. He hit three home runs in the post-season, in just 16 at bats.
Green was traded to the Arizona Diamondbacks on January 11, 2005. He waived his no-trade clause for a three-year extension from the team for $32 million. The trade was part of a three-team trade which sent Green and cash to the Diamondbacks, in exchange for catcher Dioner Navarro and three minor leaguers.