Princess Marie of Württemberg (30 October 1816 – 4 January 1887) was the eldest daughter of William I of Württemberg and Catherine Pavlovna of Russia.
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Family
Princess Marie Friederike Charlotte was the first child and eldest daughter of William I of Württemberg and Yekaterina Pavlovna of Russia. The princess was born on 30 October 1816 in Stuttgart, which was the same day her parents ascended the throne of Württemberg. Marie had a younger sister named Sophie, two half-brothers from her mother's first marriage, Aleksandr and Pyotr Georgiyevich of Oldenburg and three other half siblings, born by Marie's father's third wife, Pauline Therese of Württemberg: Katharina Friederike, Karl I and Auguste of Württemberg. According to Friedrich Wilhelm Hackländer, princess Marie was "lovely, delicated figure,... supremely graceful" and wealthy thanks to her mother's inheritance.
Marriage
On 19 March 1840, Princess Marie married Count Alfred von Neipperg. Their marriage was a love match. After marriage, Marie was allowed to retain her title and rank as a member of the royal family and possessed a large estate. The couple lived in a childless, long-distance marriage: Marie resided in Stuttgart the Princesses' Palace which was later known as the Wilhelm Palace , co-owned by her sister Sophie, and only visited the Neipperg family estate in Schwaigern with her entourage during the summer months.