Civil War
With the outbreak of the Civil War, Baylor enlisted in the Confederate States Army, joining Captain Hamner's company (Company H, 2nd Texas Mounted Rifles) at Weatherford on March 17, 1861, and was elected first lieutenant, the company being attached to Colonel John S. Ford's regiment of cavalry. He enlisted for three years and was sworn in as first lieutenant of his company in San Antonio in May 1861. His brother, John R. Baylor, was lieutenant colonel of the regiment. He went with his company to Fort Clark, and from there went to El Paso as his brother's adjutant.
Ford's regiment had four companies. It went to El Paso, there became Pyron's regiment and enlisted more men and companies, and then went to Louisiana under General Thomas Green.
Shortly after his arrival in El Paso the first regiment of the Union Army Baylor was called upon to fight was that to which his father had been attached during his lifetime, the 7th Infantry, and he and his brother had relatives and a large number of friends in its ranks. Though there were 750 men in the Union forces and a little over 300 in those of the Confederates, after a short struggle the entire Union regiment was captured.
From this time Baylor's advancement in rank was rapid. After being stationed for a short time at San Augustine Springs, in New Mexico (afterwards Cox's ranch), he received an appointment from General Albert Sidney Johnston as his chief aide-de-camp and went to join Johnston's staff at Bowling Green, Kentucky. He remained on Johnston's staff until the general was killed at Shiloh, and held his head in his dying moments.
After General Johnston's death Jefferson Davis promoted Baylor to the rank of major, with authority to raise a battalion of Texas rangers for service in the Confederate cause. The battalion was later increased to a regiment and Baylor's rank raised to that of colonel (2nd Arizona Regiment) by President Davis's order.
Baylor was present at the capture of the United States regulars near Fort Fillmore in New Mexico, and in the following fights in the Louisiana Red River campaign: Mansfield, Pleasant Hill, Monett's Ferry, Marksville, Mansura and Yellow Bayou. He took part in the pursuit of Union General Banks. Since Colonel Walter P. Lane was wounded at Mansfield, Baylor took command of the brigade until the close of the Red River campaign. Baylor's brigade captured the City Belle and the troops aboard on May 3, 1864. His brigade destroyed the USS Covington, and captured the USS Signal and transport John Warner on May 5, 1864. His troops captured the Warren, a steamboat loaded with supplies and troops going up the Red River in Louisiana. At the battle of Mansfield his regiment was in Lane's brigade which struck the right wing of the Union force. Mansfield was a smashing Confederate success, with the victors capturing 1,541 Union soldiers, 20 cannons, and 175 wagons. However, Confederate losses were substantial, including General Alfred Mouton killed. At the battle of Monett's Ferry, Baylor was assigned to take command of the left flank of the Confederate force.
While the promised regiment of Texas rangers was never raised, because of the coming of the close of the Civil War, Colonel Baylor retained his rank, and it was a dispute over this that led him to kill General John A. Wharton during a heated quarrel on April 6, 1865, at the headquarters of General John B. Magruder in the Fannin Hotel in Galveston. They argued, reportedly about "military matters" related to the reorganization of the Trans-Mississippi Department, and Wharton repeatedly struck Baylor in the face, calling him a liar; then Baylor drew his revolver and shot Wharton, who was unarmed and died instantly. Baylor was tried three times before he was finally acquitted after the war.
By his own account, Baylor was never wounded or made prisoner, but was badly scared by being hit on the nose at Shiloh on April 6, 1862, and had a horse shot under him at Yellow Bayou, Louisiana, in 1864.